Chemical Equilibrium formulas
Master Chemical Equilibrium through 22 JEE Advanced-level formulas, systematically structured with every variable spelled out. Revise concept-wise, identify the areas where you need improvement, and focus your preparation with greater precision.
Chemical Equilibrium, every formula
22 formulas, typeset and free. Print it, or keep it open beside your practice.
Equilibrium constant (concentration)
Q1MCQKcFor $aA+bB\rightleftharpoons cC+dD$, $K_c$ is:- A$\dfrac{[C]^{c}[D]^{d}}{[A]^{a}[B]^{b}}$
- B$\dfrac{[A]^{a}[B]^{b}}{[C]^{c}[D]^{d}}$
- C$[C]+[D]$
- D$[A][B]$
- A
Equilibrium constant (pressure)
Q1MCQKpThe equilibrium constant in terms of partial pressures is:- A$\dfrac{p_C^{c}p_D^{d}}{p_A^{a}p_B^{b}}$
- B$\dfrac{p_A^{a}p_B^{b}}{p_C^{c}p_D^{d}}$
- C$p_C+p_D$
- D$p_A p_B$
- A
Kp–Kc relation
Q1MCQKp–KcThe relation between $K_p$ and $K_c$ is:- A$K_p=K_c(RT)^{\Delta n_g}$
- B$K_p=K_c RT$
- C$K_p=K_c$
- D$K_p=\dfrac{K_c}{RT}$
- A
Reaction quotient
Q1MCQQThe reaction quotient $Q$ has the same form as:- A$K$ but with non-equilibrium concentrations
- B$\Delta G$
- Cthe rate constant
- Dthe activation energy
- A
Direction of reaction
Q1MCQDirectionIf $Q<K$, the reaction proceeds:- Aforward
- Bbackward
- Cat equilibrium
- Dstops
- A
Kp in terms of degree of dissociation
A₂⇌2A
Q1MCQKp and αFor $A_2\rightleftharpoons2A$ at total pressure $P$, $K_p$ is:- A$\dfrac{4\alpha^{2}}{1-\alpha^{2}}P$
- B$\dfrac{\alpha^{2}}{1-\alpha}P$
- C$\alpha^{2}P$
- D$\dfrac{\alpha}{1-\alpha}$
- A
Degree of dissociation (small)
Q1MCQSmall αFor small dissociation, $\alpha$ is approximately:- A$\sqrt{\dfrac{K_p}{P}}$
- B$\dfrac{K_p}{P}$
- C$K_p P$
- D$\dfrac{P}{K_p}$
- A
Free energy and K
Q1MCQΔG° and KThe free energy and equilibrium constant relation is:- A$\Delta G^{\circ}=-RT\ln K$
- B$\Delta G^{\circ}=RT\ln K$
- C$\Delta G^{\circ}=K$
- D$\Delta G^{\circ}=-\dfrac{RT}{K}$
- A
van't Hoff equation
Q1MCQvan't HoffThe temperature dependence of $K$ is given by:- Athe van't Hoff equation
- Bthe Arrhenius equation
- Cthe Nernst equation
- DHess's law
- A
K for reverse reaction
Q1MCQReverse KThe equilibrium constant of the reverse reaction is:- A$\dfrac{1}{K_{fwd}}$
- B$K_{fwd}$
- C$-K_{fwd}$
- D$K_{fwd}^{2}$
- A
K for a multiplied reaction
reaction multiplied by n
Q1MCQMultiplied reactionIf a reaction is multiplied by $n$, the new equilibrium constant is:- A$K^{n}$
- B$nK$
- C$\dfrac{K}{n}$
- D$K$
- A
K for added reactions
Q1MCQAdded reactionsIf two reactions are added, the overall $K$ is:- A$K_1\times K_2$
- B$K_1+K_2$
- C$\dfrac{K_1}{K_2}$
- D$K_1-K_2$
- A
Le Chatelier (pressure)
Q1MCQLe Chatelier (P)Increasing the pressure shifts equilibrium toward:- Athe side with fewer gas moles
- Bthe side with more gas moles
- Cneither side
- Dthe solid side
- A
Le Chatelier (temperature)
Q1MCQLe Chatelier (T)Increasing the temperature shifts equilibrium in the:- Aendothermic direction
- Bexothermic direction
- Cforward direction always
- Dbackward direction always
- A
Vapour density and dissociation
Q1MCQVD and dissociationThe degree of dissociation from vapour density is:- A$\dfrac{D-d}{(n-1)d}$
- B$\dfrac{D-d}{d}$
- C$\dfrac{d}{D}$
- D$D-d$
- A
Kc units
Q1MCQKc unitsThe units of $K_c$ are:- A$(\text{mol/L})^{\Delta n}$
- Bmol/L always
- Cdimensionless always
- DL/mol
- A
Equilibrium: rates equal
Q1MCQRates at equilibriumAt equilibrium, the forward and backward rates are:- Aequal
- Bzero
- Cmaximum
- Dunequal
- A
Degree of dissociation range
Q1MCQα rangeThe degree of dissociation $\alpha$ ranges from:- A$0$ to $1$
- B$-1$ to $1$
- C$0$ to $\infty$
- D$1$ to $2$
- A
Homogeneous equilibrium
Q1MCQHomogeneousA homogeneous equilibrium has all species in:- Athe same phase
- Bdifferent phases
- Cthe solid phase
- Dthe gas phase only
- A
Heterogeneous equilibrium
Q1MCQHeterogeneousIn a heterogeneous equilibrium, pure solids and liquids are:- Aexcluded from the equilibrium expression
- Bincluded with concentration
- Csquared
- Ddoubled
- A
Mole fraction & Kx
Q1MCQKp and KxThe relation between $K_p$ and $K_x$ is:- A$K_p=K_x P^{\Delta n_g}$
- B$K_p=K_x$
- C$K_p=\dfrac{K_x}{P}$
- D$K_p=K_x RT$
- A
Effect of catalyst
Q1MCQCatalystAdding a catalyst to an equilibrium:- Adoes not change $K$
- Bincreases $K$
- Cdecreases $K$
- Dshifts it forward
- A
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