Chemical Kinetics formulas
Master Chemical Kinetics through 22 JEE Advanced-level formulas, systematically structured with every variable spelled out. Revise concept-wise, identify the areas where you need improvement, and focus your preparation with greater precision.
Chemical Kinetics, every formula
22 formulas, typeset and free. Print it, or keep it open beside your practice.
Rate of reaction
Q1MCQRateFor $2A\to B$, the rate of reaction is:- A$-\tfrac12\dfrac{d[A]}{dt}$
- B$-\dfrac{d[A]}{dt}$
- C$-2\dfrac{d[A]}{dt}$
- D$\dfrac{d[A]}{dt}$
- A
Rate law
Q1MCQRate lawThe rate law of a reaction is:- A$k[A]^{m}[B]^{n}$
- B$k[A][B]$ always
- C$k[A]+[B]$
- D$k$
- A
Order of reaction
Q1NumericalOrderFor a rate law $k[A]^{2}[B]^{1}$, the overall order is:Zero-order integrated
Q1MCQZero orderThe integrated rate law for a zero-order reaction is:- A$[A]=[A]_0-kt$
- B$\ln[A]=\ln[A]_0-kt$
- C$\dfrac{1}{[A]}=\dfrac{1}{[A]_0}+kt$
- D$[A]=[A]_0 e^{-kt}$
- A
Zero-order half-life
Q1MCQZero-order t½The half-life of a zero-order reaction is:- A$\dfrac{[A]_0}{2k}$
- B$\dfrac{0.693}{k}$
- C$\dfrac{1}{k[A]_0}$
- D$\dfrac{2k}{[A]_0}$
- A
First-order integrated
Q1MCQFirst orderThe integrated first-order rate constant is:- A$\dfrac{2.303}{t}\log\dfrac{[A]_0}{[A]}$
- B$\dfrac{[A]_0-[A]}{t}$
- C$\dfrac{1}{[A]}-\dfrac{1}{[A]_0}$
- D$kt$
- A
First-order half-life
Q1MCQFirst-order t½The half-life of a first-order reaction is:- A$\dfrac{0.693}{k}$
- B$\dfrac{[A]_0}{2k}$
- C$\dfrac{1}{k[A]_0}$
- D$0.693\,k$
- A
Second-order integrated
Q1MCQSecond orderThe integrated second-order rate law is:- A$\dfrac{1}{[A]}-\dfrac{1}{[A]_0}=kt$
- B$[A]=[A]_0-kt$
- C$\ln[A]=\ln[A]_0-kt$
- D$[A]=[A]_0 e^{-kt}$
- A
Second-order half-life
Q1MCQSecond-order t½The half-life of a second-order reaction is:- A$\dfrac{1}{k[A]_0}$
- B$\dfrac{0.693}{k}$
- C$\dfrac{[A]_0}{2k}$
- D$k[A]_0$
- A
Arrhenius equation
Q1MCQArrheniusThe Arrhenius equation is:- A$k=A\,e^{-E_a/RT}$
- B$k=A\,e^{E_a/RT}$
- C$k=\dfrac{A}{E_a}$
- D$k=AE_a T$
- A
Arrhenius (log form)
Q1MCQArrhenius logThe logarithmic Arrhenius form is:- A$\ln k=\ln A-\dfrac{E_a}{RT}$
- B$\ln k=\ln A+\dfrac{E_a}{RT}$
- C$\ln k=\dfrac{E_a}{RT}$
- D$\ln k=A$
- A
Two-temperature Arrhenius
Q1MCQTwo-T ArrheniusThe two-temperature Arrhenius relation is:- A$\ln\dfrac{k_2}{k_1}=\dfrac{E_a}{R}\left(\dfrac{1}{T_1}-\dfrac{1}{T_2}\right)$
- B$\ln\dfrac{k_2}{k_1}=\dfrac{E_a}{R}(T_2-T_1)$
- C$\dfrac{k_2}{k_1}=e^{E_a}$
- D$k_2=k_1$
- A
Temperature coefficient
Q1MCQTemperature coefficientFor a $10$ K rise, the rate constant typically:- Aincreases 2–3 times
- Bhalves
- Cis unchanged
- Dincreases 10 times
- A
Units of rate constant
Q1MCQUnits of kThe units of the rate constant of an $n$th-order reaction are:- A$(\text{mol/L})^{1-n}\text{s}^{-1}$
- B$\text{s}^{-1}$
- C$\text{mol/L}$
- Ddimensionless
- A
Rate constant (zero order)
Q1MCQZero-order unitsThe units of $k$ for a zero-order reaction are:- A$\text{mol L}^{-1}\text{s}^{-1}$
- B$\text{s}^{-1}$
- C$\text{L mol}^{-1}\text{s}^{-1}$
- Ddimensionless
- A
Rate constant (first order)
Q1MCQFirst-order unitsThe units of $k$ for a first-order reaction are:- A$\text{s}^{-1}$
- B$\text{mol L}^{-1}\text{s}^{-1}$
- C$\text{L mol}^{-1}\text{s}^{-1}$
- Ddimensionless
- A
Molecularity
Q1MCQMolecularityMolecularity is the number of species in:- Aan elementary step
- Bthe overall reaction
- Cthe products
- Dthe catalyst
- A
Fraction remaining (first order)
Q1MCQFraction remainingFor a first-order reaction, the fraction remaining is:- A$e^{-kt}$
- B$1-kt$
- C$\dfrac{1}{kt}$
- D$kt$
- A
Activation energy from graph
Q1MCQEa from graphThe slope of $\ln k$ versus $\dfrac{1}{T}$ is:- A$-\dfrac{E_a}{R}$
- B$\dfrac{E_a}{R}$
- C$E_a$
- D$\ln A$
- A
Average rate
Q1NumericalAverage rateIf $[A]$ falls from $0.8$ to $0.6$ M in $2$ s, the average rate (M/s) is:Time for nth-life (first order)
Q1NumericalFirst-order t½ calcA first-order reaction has $k=0.0693\ \text{s}^{-1}$. Its half-life (s) is:Threshold energy
Q1MCQThreshold energyThe threshold energy equals:- A$E_a+E_{reactants}$
- B$E_a-E_{reactants}$
- C$E_a$
- D$E_{reactants}$
- A
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